Crystals in Glass: A Hidden Beauty
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About this ebook
A "must-have" for materials engineers, chemists, physicists, and geologists, this is one of the first "coffee-table" books in the field of glass science.
Containing over fifty beautiful micrographs, the book reflects 35 years of original research by a highly regarded authority in the field. It contains 50 slides culled from tens of thousands of images on glass crystal nucleation, growth, and crystallization. The images represent glass crystallization mechanisms, including internal, surface, homogeneous, heterogeneous, and eutectic, crystal nucleation and growth.
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Crystals in Glass - E. D. Zanotto
Cover Design: John Wiley & Sons, Inc.
Cover Photograph: © Edgar D. Zanotto
Copyright © 2013 by John Wiley & Sons, Inc. and The American Ceramic Society. All rights reserved.
Published by John Wiley & Sons, Inc., Hoboken, New Jersey.
Published simultaneously in Canada.
No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com. Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permission.
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Library of Congress Cataloging-in-Publication Data:
Zanotto, E. D. (Edgar Dutra)
Crystals in glass : a hidden beauty / by Edgar D. Zanotto.
pages cm Includes bibliographical references and index.
ISBN 978-1-118-52143-4 (cloth : alk. paper) 1. Glass-ceramics. 2. Silicate crystals.
3. Nucleation. 4. Crystallization. I. Title.
TP862.Z36 2013
660'.284298-dc23 2012045177
Printed in Singapore.
10 9 8 7 6 5 4 3 2 1
Contents
Title
copyright
Dedication
Introduction
Acknowledgme
About the Author
Reviews of Crystals in Glass: A Hidden Beauty
Foreword
Chapter 1: Crystals in Glass
Part 1: Interna Nucleation In Glasses
Lithium Disilicate Crystals in an Isochemical Glass
Spherulitic Crystals in a Stoichiometric Barium Disilicate Glass
Internal Crystallization in Ti-cordierite Glass
Papaya-seed-like Nanocrystals in Fresnoite Glass
Lithium Diborate Crystals in an Isochemical Glass
Internal Crystal in a Diopside Glass
Lithium Niobium Disilicate (Double) Crystals in a Nonstoichiometric Glass
Crystals in Li2O-Doped Soda-lime-silica Glasses
Textured Worm-like Crystals in a Bioactive Glass Fiber
Liquid-liquid Phase Separation and Crystallization in Photo-thermo-refractive Glass
Star-like Crystals in the Volume of PTR Glass
Cristobalite Crystals in PTR Glass
Surface Layer and Internal Crystallization in PTR Glass
The Courtyard Effect in Stoichiometric Soda-lime-silica Glass
The Courtyard Effect in Stoichiometric Soda-lime-silica Glass
The Courtyard Effect—LS Crystals in a Eutectic Glass
Hematite Crystals in Soda-lime-silica Glass
Ionic Conducting Glass-ceramics
Part 2: Surface Nucleation on Glasses
Surface Crystallization of Lithium Diborate Glass
Cordierite Crystal on the Surface of a Cordierite Glass
Surface Nucleation on Cordierite Glass
Nucleation on Scratches, Cracks, and Bubbles
Crystals on Bubble Surfaces in a Diopside Glass
Surface Crystallization on a Calcium Phosphate Glass
Surface Crystallization on Ca-rich Diopside Glass
Surface Crystallization on Ca-rich Diopside Glass
Wollastonite Needles in a Commercial